Chloridobis[diphenylglyoximato(1–)-κ2 N,N′](1H-imidazole-κN 3)cobalt(III) hemihydrate
نویسندگان
چکیده
The Co centre in the title compound, [Co(C(14)H(11)N(2)O(2))(2)Cl(C(3)H(4)N(2))]·0.5H(2)O, shows a slightly distorted octa-hedral coordination geometry. The glyoximate units of the mol-ecule are linked by O-H⋯O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through inter-molecular N-H⋯O, N-H⋯N and O-H⋯Cl hydrogen bonds. The uncoordinated water mol-ecule shows half-occupation.
منابع مشابه
(N 4-n-Butylpyridine-4-carbothioamide-κN 4)chloridobis(dimethylglyoximato-κ2 N,N′)cobalt(III) hemihydrate
The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean ...
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